Chile are to play European champions Spain in a friendly in November, the Chilean Football Association has announced.
ANFP secretary general Jorge Contador said that the Spanish Football Federation (RFEF) had written to ANFP president Harold Mayne-Nicholls to confirm the fixture on November 19.
A venue is yet to be confirmed.
On Wednesday, Chile lost 1-0 away to Turkey, while Spain won 3-0 away in Denmark.
Spain begin their World Cup qualifying campaign in September against Bosnia-Herzegovina, and have also been drawn against Armenia, Belgium, Estonia and Turkey in Group Five.
Chile play Brazil on September 7 when they resume their own qualification campaign, having collected 10 points from their opening six games to sit fourth in the table.